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Committee Member: search.filters.committeemember.Salac, Edcyl LeeDegree: search.filters.degree.Bachelor of Science in Chemistry

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    Physicochemical characterization and FTIR Analysis of the essential oil from Almaciga (Agathis philippinensis Warb) gum
    Briones, Kathleen Faith C. (Department of Chemistry, College of Arts and Sciences, University of the Philippines Visayas, 2016-02)
    Almaciga (Agathis philippinensis ) is one of the few conifer timber species endemic to the Philippines. It is highly valued for its resin which is the world- renowned Manila copal (hard resin). Manila copal have been reportedly employed in treating asthma, headaches, myalgia and even arthritis. An ethnomedical documentation of Manila copal usage also reported the utilization of the resin for stomachache, ulcers and dysentery. However, there is only limited literature regarding the Almaciga gum (the softer resin). To provide supplemental data regarding the Almaciga gum, this study was conducted to characterize the physicochemical properties and to identify the major functional groups of the essential oil extracted from its resin. The essential oil was extracted using a makeshift steam distillation set- up with a total yield of 3.20%. The essential oil was found to have a refractive index of 1.4731± 0.0002, a density of 0.8502±0.0039 g/mL, and a specific gravity of 0.8527±0.0039. Odor, color and appearance were evaluated using the organoleptic method. Major functional groups were identified from Fourier Transform - Infrared Spectroscopy (FTIR) which suggested that limonene is the major component.
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    Antioxidant property of anthocyanin from malatinta (Phyllanthus reticulatus Poir.) fruits obtained by static and microwave-assisted extraction
    Baldonasa, RB Hera Angelica R. (Department of Chemistry, College of Arts and Sciences, University of the Philippines Visayas, 2015-06)
    Fresh fruits of Phyllanthus reticulatus Poir. were analyzed for anthocyanin by spectrophotometric method. The antioxidant activity using 1,1 -diphenyl-2-picrylhydrazyl (DPPH ) free radical scavenging activity (FRSA) and reducing power (RP) through FeCl3 assay were determined. The use of two extraction processes, namely, the static method and microwave-assisted extraction, using two extraction solvents, acidified methanol and aqueous ethanol (1:1) were compared. The total anthocyanin content (TAC) of P. reticulatus fruit was highest in extract using static method of extraction in acidified methanol solvent (279.94 ±17.31 mg/lOOg), comparable to levels found in plants rich in anthocyanins, (e.g., berries genotypes, grapes and red cabbages). In microwave-assisted extraction, TAC using acidified methanol was higher (278.01 ± 18.76 mg/lOOg) compared to using aqueous ethanol (210.96 ± 2.02 mg/100g). P. reticulatus fruits exhibited high antioxidant activity as revealed by its RP and DPPH FRSA results when compared to ascorbic acid. These findings highlight the usefulness of P. reticulatus as a source of anthocyanins with good antioxidant properties, which, in turn, gives importance to the undervalued and underutilized plant.