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    Assessment of heavy metal traces (Copper and lead) in the soft tissue of Oysters Crassostrea virginica
    Balboa, Dexter G. (Division of Biological Sciences, College of Arts and Sciences, University of the Philippines Visayas, 2010-04-05)
    The bivalve mollusk Crassostrea virginica is abundant in Brgy. Calaparan, Arevalo and Brgy. Bacong, Dumangas; and are widely consumed by the residence as food. Bioaccumulation of Copper and Lead in the soft tissues of C. virginica from Brgy. Calaparan, Arevalo and Brgy. Bacong, Dumangas were measured and checked if they are still within the permissible levels of Copper and Lead in food based on Median International Standards for metals compiled by the Food and Agricultural Organization of the United Nations. Metal concentrations (μg/g) were determined using Flame Atomic Absorption Spectrophotometer. Mean concentrations of the heavy metals in C. virginica from Calaparan, Arevalo- Cu 27.829, Pb 1.2133; Bacong, Dumangas- Cu 57.834, Pb 0.1338. These levels of Copper and Lead in oyster tissue from both sites are within the the range of Median International Standards for metals and are safe for human consumption. Statistical analysis through one- way ANOVA (F > Fcrit, showed significant difference between sites (Fcrit = 18.51282) for Copper (F value, 215.06569) but not for Lead (F value, 2.25151). The study also provided further solid evidence that bivalve like Crassostrea virginica can recover and concentrate environmentally derived and anthropogenic traces of heavy metals.
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    Optimization of lead (II) adsorption of EDTA-functionalized magnetic graphene oxide using response surface methodology
    Angeles, Christine Debbie Shanne V. (Department of Chemistry, College of Arts and Sciences, University of the Philippines Visayas, 2017-06)
    Chronic intake of lead-contaminated water, even at low concentrations, can cause damage to the digestive, reproductive, and nervous systems. To effectively remove lead in water, solid phase extraction or adsorption is being used. In this study, EDTA-functionalized magnetic graphene oxide (EmGO) adsorbent was fabricated using a stepwise modification of graphene oxide (GO). It was characterized using SEM, FTIR, and XRD. EmGO was shown to have improved adsorption capacity towards Pb(II) in natural water. Also, the magnetic property of the adsorbent allowed an easier and more convenient mean of retrieval. The generated response surface model from Box- Behnken design (BBD) approximated the optimum condition for maximum removal efficiency of EmGO. Based on the results, the model had a 0.9113 (±0.0001) overall desirability, optimum values for pH, adsorbent dosage, and contact time were 5.99 (±0.01), 12.2135 (±0.0001), and 48.39 (±0.01), respectively. The highest percent removal efficiency of EmGO in the experiment was determined to be 73.41 (±0.01)%.